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Synlett 2001; 2001(3): 0394-0396
DOI: 10.1055/s-2001-11392
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Design of Multinuclear Chiral Organoaluminum Complexes with (R)-Binaphthol Derivatives

Kazuaki Ishihara* , Jun Kobayashi, Kazato Inanaga, Hisashi Yamamoto
  • *Research Center for Advanced Waste and Emission Management, Nagoya University, Furo-cho, Chikusa, Nagoya 464-8603, Japan; Fax + 81(52)7 89 32 22; E-mail: yamamoto@cc.nagoya-u.ac.jp
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Publication Date:
31 December 2001 (online)

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Chiral dialuminum and trialuminum Lewis acids, which are effective as asymmetric Diels-Alder catalysts, have been prepared from organoaluminum reagents and optically pure binaphthol derivatives.

multinuclear - organoaluminum - chiral Lewis acid - Diels-Alder reaction - catalyst