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Synlett 2001; 2001(4): 0529-0531
DOI: 10.1055/s-2001-12337
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1,6-Asymmetric Induction during the Conjugate Addition of Arylcopper Reagents to Chiral Sulfinyl-substituted Pyrrolyl α,β-Unsaturated Enones

Yoshitsugu Arai* , Kimio Ueda, Jianhua Xie, Yukio Masaki
  • *Gifu Pharmaceutical University, 5-6-1 Mitahora-higashi, Gifu 502-8585, Japan; Fax + 81-58-237-5979; E-mail: araiy@gifu-pu.ac.jp
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Publication Date:
31 December 2001 (online)

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Asymmetric conjugate additions of arylcopper reagents, derived from aryl Grignard reagents and copper(I) iodide, to a chiral sulfinyl pyrrolyl α,β-unsaturated enones have been achieved.

aryl copper - conjugate additions - diastereoselectivity - pyrrolyl sulfoxides