Abstract
Organotellurium compounds serve as excellent precursors for carbon-centered radicals,
which have significant synthetic utility ranging from the formation of highly functionalized
small molecules to structurally well-defined macromolecules. This review focuses on
the radical reactions of organotellurium compounds, with an emphasis on the new carbon-carbon
bond formation reaction developed in the author’s laboratory.
1 Introduction
2 Reversible Radical Generation from Organotellurium Compounds
3 Radical Addition to Unsaturated Carbon-Carbon Bonds
3.1 Glycosyl Radical Addition to Alkynes
3.2 Functionalization of Quinones
3.3 Group-Transfer Imidoylation of Isonitriles
4 Silyltelluride-Mediated Radical Coupling Reactions
4.1 Coupling of Carbonyl Compounds with Isonitriles
4.2 Coupling of Carbonyl Compounds with Alkynes
4.3 Coupling of Imines with Isonitriles
4.4 Reductive bis-Silylation of Quinones
5 Living Radical Polymerization
5.1 Development of New Initiators
5.2 Confirmation of Living Character
5.3 Selective Modification of Polymer-End Group
5.4 Development of High-Speed TERP
6 Summary
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