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Synlett
DOI: 10.1055/a-2579-3319
DOI: 10.1055/a-2579-3319
letter
Nickel-Catalyzed Nucleophilic Substitution of Cyclopropenes by Secondary Phosphines
We thank the National Natural Science Foundation of China (NSFC; grant numbers 22071224 and 22471251), and the Chinese Academy of Sciences (CAS) Project for Young Scientists in Basic Research (YSBR-098) for financial support.
Abstract
Research on the efficient synthesis of allylphosphine compounds is of crucial significance. Herein, a nickel-catalyzed ring-opening of cyclopropenes is described to synthesize allylphosphine compounds. This transformation enables a mild and efficient preparation of allylphosphine compounds in good yields, with 100% atom efficiency.
Key words
nickel catalysis - hydrophosphination - secondary phosphines - allylphosphine - C–P constructionSupporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-2579-3319.
- Supporting Information
Publication History
Received: 26 February 2025
Accepted after revision: 09 April 2025
Accepted Manuscript online:
09 April 2025
Article published online:
03 June 2025
© 2025. Thieme. All rights reserved
Georg Thieme Verlag KG
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