Visible-Light-Induced I₂-Mediated Cyclization of ortho-Biarylchalcones of Naphthofuran Series toward Oxa[5]helicenes

Abstract

This work presents a novel, eco-friendly, transition metal-free method for synthesizing oxa[5]helicenes via visible-light-induced photocyclization of ortho-biarylchalcones of naphthofuran series. It was found that the obtained compounds are highly stable to both UV (365 nm) and visible light (LED420) irradiation in the presence of atmospheric oxygen or molecular iodine.

Keywords

Photochemistry - Heterocycles - Biarylchalcones - Naphthofuran - Photocyclization - Mallory reaction - Helicenes

Publikationsverlauf

Eingereicht: 15. Mai 2025

Angenommen nach Revision: 25. Juni 2025

Accepted Manuscript online:
25. Juni 2025

Artikel online veröffentlicht:
07. August 2025

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