Heck Arylations of Baylis-Hillman Adducts

Abstract

This short review examines the palladium-catalyzed arylation of the C=C bond of Baylis-Hillman adducts. It summarizes the different intermolecular and intramolecular reaction procedures, and contains detailed tables making it easier to compare their efficiency.

1 Introduction

2 Intermolecular Reactions

2.1 Without Decarboxylation

2.2 With Decarboxylation

3 Intramolecular Reactions

4 Conclusions

catalysis - palladium - Heck arylation - Baylis-Hillman - cyclization - decarboxylation

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