Woollins Reagent: A Chemoselective Reducing Agent for 1,4-Enediones and 1,4-Ynediones to Saturated 1,4-Diones

Madhumita Mandal; Sourav Chatterjee; Parasuraman Jaisankar

doi:10.1055/s-0032-1317343

Synlett, Inhaltsverzeichnis

Synlett 2012; 23(18): 2615-2618
DOI: 10.1055/s-0032-1317343

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Woollins Reagent: A Chemoselective Reducing Agent for 1,4-Enediones and 1,4-Ynediones to Saturated 1,4-Diones

Madhumita Mandal

Department of Chemistry, CSIR-Indian Institute of Chemical Biology, 4, Raja S. C. Mullick Road, Calcutta 700032, India Fax: +91(33)24735197 eMail: jaisankar@iicb.res.in

,

Sourav Chatterjee

Department of Chemistry, CSIR-Indian Institute of Chemical Biology, 4, Raja S. C. Mullick Road, Calcutta 700032, India Fax: +91(33)24735197 eMail: jaisankar@iicb.res.in

,

Parasuraman Jaisankar*

Department of Chemistry, CSIR-Indian Institute of Chemical Biology, 4, Raja S. C. Mullick Road, Calcutta 700032, India Fax: +91(33)24735197 eMail: jaisankar@iicb.res.in

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Abstract

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Abstract

Woollins reagent was found to act as a highly chemoselective reagent for the reduction of a wide range of 1,4-enediones and 1,4-ynediones in methanol to afford the corresponding saturated 1,4-diketones in good yields under mild reaction conditions.

Key words

Woollins reagent - chemoselective reduction - 1,4-enediones - 1,4-ynediones - 1,4-diketones

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Referenzen

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