Scalable Synthesis of Pure and Stable Hexaaminobenzene Trihydrochloride

Javeed Mahmood; Dongwook Kim; In-Yup Jeon; Myoung Soo Lah; Jong-Beom Baek

doi:10.1055/s-0032-1317696

Synlett, Inhaltsverzeichnis

Synlett 2013; 24(2): 246-248
DOI: 10.1055/s-0032-1317696

letter

Scalable Synthesis of Pure and Stable Hexaaminobenzene Trihydrochloride

Authors

Javeed Mahmood

Interdisciplinary School of Green Energy/Low-Dimensional Carbon Materials Center, Ulsan National Institute of Science and Technology (UNIST), 100 Banyeon, Ulsan, 689-798, South Korea Fax: +82(52)2172019 eMail: jbbaek@unist.ac.kr eMail: mslah@unist.ac.kr
Dongwook Kim

Interdisciplinary School of Green Energy/Low-Dimensional Carbon Materials Center, Ulsan National Institute of Science and Technology (UNIST), 100 Banyeon, Ulsan, 689-798, South Korea Fax: +82(52)2172019 eMail: jbbaek@unist.ac.kr eMail: mslah@unist.ac.kr
In-Yup Jeon

Interdisciplinary School of Green Energy/Low-Dimensional Carbon Materials Center, Ulsan National Institute of Science and Technology (UNIST), 100 Banyeon, Ulsan, 689-798, South Korea Fax: +82(52)2172019 eMail: jbbaek@unist.ac.kr eMail: mslah@unist.ac.kr
Myoung Soo Lah*

Interdisciplinary School of Green Energy/Low-Dimensional Carbon Materials Center, Ulsan National Institute of Science and Technology (UNIST), 100 Banyeon, Ulsan, 689-798, South Korea Fax: +82(52)2172019 eMail: jbbaek@unist.ac.kr eMail: mslah@unist.ac.kr
Jong-Beom Baek*

Interdisciplinary School of Green Energy/Low-Dimensional Carbon Materials Center, Ulsan National Institute of Science and Technology (UNIST), 100 Banyeon, Ulsan, 689-798, South Korea Fax: +82(52)2172019 eMail: jbbaek@unist.ac.kr eMail: mslah@unist.ac.kr

Abstract

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Abstract

Synthesis of hexaaminobenzene (HAB) in pure and stable form has remained as an important challenge for a long time, since it is a fascinating synthon for the synthesis of aromatic nitrogenous compounds having many interesting applications. Here, we report an improved synthesis of pure and stable HAB form using modified catalytic hydrogenation in aqueous acidic medium. The structure of needle-shaped HAB crystals was confirmed by single-crystal X-ray diffraction study. The synthetic protocol could thus be a simple, but efficient for the large-scale synthesis of highly pure and stable HAB.

Key words

hexaaminobenzene - palladium - reduction - TATB - TNA

Volltext

Referenzen

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