Synlett 2013; 24(16): 2085-2088
DOI: 10.1055/s-0033-1339683
letter
© Georg Thieme Verlag Stuttgart · New York

Iron-Catalyzed Direct C(sp3)–H Amination Reactions of Isochroman Derivatives with Primary Arylamines under Mild Conditions

Di Chen
a   School of Pharmaceutical and Chemical Engineering, Taizhou University, Taizhou 317000, P. R. of China   Fax: +86(576)85137075   Email: yjg@tzc.edu.cn
,
Fuyou Pan
a   School of Pharmaceutical and Chemical Engineering, Taizhou University, Taizhou 317000, P. R. of China   Fax: +86(576)85137075   Email: yjg@tzc.edu.cn
,
Jianrong Gao
b   College of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou 310014, P. R. of China
,
Jianguo Yang*
a   School of Pharmaceutical and Chemical Engineering, Taizhou University, Taizhou 317000, P. R. of China   Fax: +86(576)85137075   Email: yjg@tzc.edu.cn
› Author Affiliations
Further Information

Publication History

Received: 25 June 2013

Accepted after revision: 06 August 2013

Publication Date:
05 September 2013 (online)


Abstract

A direct C(sp3)–H amination reaction of isochroman derivatives with arylamines was developed in the presence of iron(II) salt. A variety of isochroman derivatives and primary amines were selectively transformed into the corresponding oxidative coupling products in good to excellent yield under mild conditions

Supporting Information

 
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