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Synlett 2014; 25(15): 2133-2138
DOI: 10.1055/s-0034-1378519
DOI: 10.1055/s-0034-1378519
letter
Ligand-Assisted Copper-Catalyzed Oxidative Cross-Coupling of Simple Phenols with Formamides for the Synthesis of Carbamates
Further Information
Publication History
Received: 22 April 2014
Accepted after revision: 20 June 2014
Publication Date:
31 July 2014 (online)
Abstract
An oxidative approach for the synthesis of phenyl carbamates has been achieved by ligand-assisted copper-catalyzed cross-dehydrogenative coupling (CDC) of phenols with formamides. The direct coupling of simple phenols with mono- and dialkyl formamides provides carbamate products in moderate to good yields under mild reaction conditions.
Supporting Information
- for this article is available online at http://www.thieme-connect.com/products/ejournals/journal/ 10.1055/s-00000083.
- Supporting Information
-
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