Hyperbranched Polyamines: Tunable Catalysts for the Henry Reaction

Subramaniapillai Selva Ganesan; Asaithampi Ganesan; Jagatheeswaran Kothandapani

doi:10.1055/s-0034-1378534

Synlett, Table of Contents

Synlett 2014; 25(13): 1847-1850
DOI: 10.1055/s-0034-1378534

letter

Hyperbranched Polyamines: Tunable Catalysts for the Henry Reaction

Authors

Subramaniapillai Selva Ganesan*

School of Chemical and Biotechnology, SASTRA University, Thanjavur-613401, India Fax: +91(4362)264120 Email: selva@biotech.sastra.edu
Asaithampi Ganesan

School of Chemical and Biotechnology, SASTRA University, Thanjavur-613401, India Fax: +91(4362)264120 Email: selva@biotech.sastra.edu
Jagatheeswaran Kothandapani

School of Chemical and Biotechnology, SASTRA University, Thanjavur-613401, India Fax: +91(4362)264120 Email: selva@biotech.sastra.edu

Abstract

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Abstract

Hyperbranched polyethylenimine derivatives were successfully employed as catalyst in the Henry reaction. The nitroalcohol products were obtained in excellent yields within short reaction times. A one-pot synthesis of β-nitrostyrenes was developed by using ZnCl₂ along with hyperbranched polyethylenimine derivatives.

Key words

Henry reaction - diastereoselectivity - polyamine - homogeneous catalysis - β-nitrostyrene

Full Text

References

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Supplementary Material

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