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Synlett 2014; 25(17): 2471-2474
DOI: 10.1055/s-0034-1379001
DOI: 10.1055/s-0034-1379001
letter
Synthetic Studies toward Lindenane-Type Sesquiterpenoid Dimers
Further Information
Publication History
Received: 14 June 2014
Accepted after revision: 26 July 2014
Publication Date:
25 August 2014 (online)
Abstract
The key transformation for the total synthesis of the lindenane sesquiterpenoid dimers is the intermolecular Diels–Alder reaction between two lindenane-type monomers. Herein we report our efforts made on examination of the biogenetic hypothesis and the inverse-electron-demand Diels–Alder (IEDDA) reaction. The combination of Tf2NH/AlMe3 was developed to catalyze the model IEDDA reaction.
Supporting Information
- for this article is available online at http://www.thieme-connect.com/products/ejournals/journal/ 10.1055/s-00000083.
- Supporting Information
-
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