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Synlett 2018; 29(03): 364-368
DOI: 10.1055/s-0036-1590925
DOI: 10.1055/s-0036-1590925
letter
Visible-Light-Induced Chemoselective Synthesis of α-Chloro and Vinyl Sulfones by Sulfonylation of Alkenes
Autoren
The authors gratefully acknowledge the Natural Science Foundation of Jiangsu Province, China (BK20160164) for financial support.
Weitere Informationen
Publikationsverlauf
Received: 28. Juli 2017
Accepted after revision: 11. September 2017
Publikationsdatum:
20. Oktober 2017 (online)
Abstract
Direct sulfonylation between alkenes and sulfonyl chloride was achieved at room temperature by a visible-light-induced photoredox process. This method allows the chemoselective synthesis of α-chloro and vinyl sulfone derivatives with moderate to high yields. The selectivity of the reaction was fully controlled by the electronic properties of the alkenes.
Key words
visible-light-induced reaction - atom-transfer radical addition - sulfonylation of alkenes - chemoselectivity - α-Chloro sulfones - vinyl sulfonesSupporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0036-1590925.
- Supporting Information (PDF) (opens in new window)
-
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