Total Syntheses of Spirooliganones A and B

Abstract

This paper describes the total syntheses of spirooliganones A and B, which provides control over the stereochemistry of the spiro center via a cascade reaction involving the in situ formation of an o-quinone methide and a hetero-Diels–Alder reaction.

Key words

total synthesis - spirooliganones A and B - spiro center - hetero-Diels–Alder reaction - {¹⁹F}-¹H HOESY

Publikationsverlauf

Eingereicht: 10. Dezember 2021

Angenommen nach Revision: 07. Februar 2022

Artikel online veröffentlicht:
08. März 2022

• References and Notes

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