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DOI: 10.1055/s-2002-34240
Advances and Adventures in Amination Reactions of Olefins and Alkynes
Publication History
Publication Date:
23 September 2002 (online)

Abstract
Recent developments in the area of transition metal-catalyzed amination of olefins and alkynes are reviewed. Special emphasis is given to rhodium-catalyzed oxidative aminations of aromatic olefins.
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1 General
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1.1 Background
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1.1.1 The Fundamental Chemistry
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1.1.2 Catalytic Amination: General Features
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1.1.2.1 Late Transition Metal-catalyzed Oxidative Amination
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1.1.2.2 Transition Metal-catalyzed Hydroamination
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1.2 Challenges and Motivation
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2 Studies at our Laboratory
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2.1 Transition Metal-catalyzed Amination of Olefins
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2.1.1 Intermolecular anti-Markovnikov Amination of
non-Activated Aryl Olefins -
2.1.2 Intermolecular anti-Markovnikov Amination of 2-Vinylpy ridine
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2.1.3 Reaction Mechanism and Catalytic Cycle
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2.1.4 Other Synthetic Applications
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2.1.4.1 Amination of Styrenes with Primary Amines (Anilines) to Form Quinolines
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2.1.4.2 Amination of Norbornadiene with Secondary Amines
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2.2 Amination of Alkynes
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3 Conclusions
Key words
aminations - amines - homogeneous catalysis - olefins - alkynes
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