New Solid Phase Triorganogermanium Hydrides for Radical Synthesis

W. Russell Bowman; Sussie L. Krintel; Mark B. Schilling

doi:10.1055/s-2004-825585

LETTER

New Solid Phase Triorganogermanium Hydrides for Radical Synthesis

W. Russell Bowman*^a, Sussie L. Krintel^a, Mark B. Schilling^b
^a Department of Chemistry, Loughborough University, Loughborough, Leics. LE11 3TU, UK
Fax: +44(1509)223925; e-Mail: w.r.bowman@lboro.ac.uk ;
^b Process Development, GlaxoSmithKline, Gunnels Wood Road, Stevenage, Herts SG1 2NY, UK

Abstract

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Abstract

New solid phase triorganogermanium hydrides have been synthesized by the addition of a simple triorganogermanium hydride unit onto Quadragel^TM and Merrifield resins. The new solid phase germanium hydrides have been used to mediate a range of synthetic radical reactions.

Key words

solid-phase synthesis - triorganogermanium hydride - radicals - radical reactions - triorganogermanium radicals

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References

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