Selectivity Controls in the [4+2] Cycloadditions of 1-Oxygenated Dienes

Jacques Maddaluno

doi:10.1055/s-2006-950445

ACCOUNT

Selectivity Controls in the [4+2] Cycloadditions of 1-Oxygenated Dienes

Jacques Maddaluno*
Laboratoire des Fonctions Azotées & Oxygénées Complexes de l’IRCOF, UMR 6014 CNRS, Université et INSA de Rouen, 76821 Mont St Aignan Cedex, France
Fax: +33(2)35522971; e-Mail: jmaddalu@crihan.fr;

Abstract

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Abstract

A selection of examples illustrating the specific reactivity and selectivity of 1-oxygenated dienes in the Diels-Alder cycloadditions is proposed.

1 Introduction

2 Reactivity, Regio- and Endoselectivity

3 Diastereoselectivity

3.1 Chiral Dienes

3.2 Chiral Dienophiles

3.3 Double Cycloadditions of Bisdienes

4 Enantioselectivity

5 Intramolecular Cycloadditions

Key words

dienes - cycloaddition - Diels-Alder reactions - regioselectivity - diastereoselectivity

Full Text

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