Synfacts

Issue 06 · June 2017

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Pyrrolidine Synthesis through C(sp³)–H Alkenylation of Aliphatic Amines

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Synthesis of Trifluoromethylated Piperazines from Aziridines

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Synthesis of Polysubstituted Furans

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Catalytic C–H Activation of Heterocycles

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Synthesis of 2,3-Dihydroimidazo[1,2-a]-pyridines by a Formal [4+2] Cyclization

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Synthesis of Kealiinine Alkaloids from Propargylguanidines

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Nickel-Catalyzed Synthesis of Benzoisoselenazolones

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Gearing Up for Switchable Machines

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Stepwise Two-Photon Photochemical Reactions

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Palladium-Catalyzed Vinylborylation of Alkenes
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Iridium-Catalyzed Asymmetric C–C Bond-Forming Transfer Hydrogenation

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Desymmetrization of meso-Anhydrides by Dual Catalysis

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Iridium-Catalyzed Asymmetric Hydrogenation of γ-Hydroxylactams

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Synthesis of Five-Membered Ring through an Alkynylation/Cyclization Step

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Rhodium-Catalyzed Enantioselective Isomerization of meso-Oxabicycles

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Rhodium-Catalyzed Enantioselective Synthesis of Spiropyrazolones

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Palladium-Catalyzed Enantioselective Syn-thesis of Chiral Biaryl Compound Precursors

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Ruthenium-Catalyzed Asymmetric Hydrogenation of Aryl N-Heteroaryl Ketones

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Hydrogenation of Cyclic Imines by a Cationic Ruthenium Diamine Catalyst

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Enantioselective Synthesis of Isochromenes by Copper/Ruthenium Tandem Catalysis

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Iridium-Catalyzed Asymmetric Reductive Amination of Aliphatic Ketones

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Asymmetric Organo-Metal Cooperative Catalysis

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Stereoselective Mizoroki–Heck Alkenylations and Arylations

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Enantioselective Addition of Enynes to Ketones

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Ruthenium-Catalyzed DKR of Benzofuranones by Transfer Hydrogenation

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Palladium-Catalyzed Synthesis of Chiral Allylboron Reagents

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Rhodium-Catalyzed Asymmetric Isomerization of Allylic Alcohols

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Synthesis of Chiral γ-Lactams by Asymmetric Hydrogenation

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Rhodium-Catalyzed Enantioselective Synthesis of Succinic Anhydrides

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Ruthenium-Catalyzed Enantioselective Si–H Bond Insertion

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Palladium-Catalyzed Enantioselective Carbene Insertion

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Exclusive Metal-Centered Chirality for Asymmetric Catalysis

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Asymmetric Formal [3+2] Cycloaddition Catalyzed by a Chiral Cobalt(II) Complex

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Synthesis of Epoxypyrrolidines by [2+1] Cycloaddition

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Palladium-Catalyzed Stereoselective C–H Olefination of Biaryls

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Zinc-Catalyzed Enantioselective Alkyne Addition

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Olefination of Sulfonyl Halides and Esters

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para-Selective C–H Borylation of Benzamides and Pyridines

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Stereoselective Synthesis of Alkylidene Cyclopentylamines

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Stereocontrolled Allylboration of Iminoisatins

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Stereospecific Rhodium-Catalyzed Allylic Alkylation

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Transition-Metal-Free Direct C–H Arylation of Quinoxalin-2(1H)-ones

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Diastereoselective Synthesis of anti- and syn-β-Aminonitriles

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Rearrangements of Cyclopropanols

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Iron-Catalyzed Borylation

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Iron-Promoted Hydroalkynylation

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Synthesis of 3-Aryl or Alkyl 1,2-Benzisoxazoles

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Iron-Catalyzed C–C Bond-Forming Spirocyclizations

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Synthesis of Functionalized β-Keto Aryl Thioethers

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Transition-Metal-Free Diboration

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Brønsted Acid Catalyzed Hydro-functionalization of Unactivated Alkynes

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Brønsted Acid Catalyzed [2+2] Photocycloaddition Reactions

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Regioselective Organocatalytic Olefin Hydroamination with 1,2,3-Triazoles

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Catalytic Enantioselective N-Alkylation of Indoles by Aza-para-quinone Methides

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Asymmetric Catalysis via Cyclic Aliphatic Oxocarbenium Ions

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N-Heterocyclic Carbene Catalyzed Truce–Smiles Rearrangement

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C–H Pyridination with Organoselenium Catalysts

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A Systematic Investigation of Intramolecular Sulfenofunctionalizations of Alkenes

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Visible-Light-Promoted [2+2+2] Cyclization of Alkynes with Nitriles

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0655
Organocatalytic Redox Deracemization of Cyclic Benzylic Ethers

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Polymer-Supported Synthesis
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One-Pot Cascade Reaction Using Crosslinked Lipase-Supported Palladium Nanoparticles

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Synthesis of Pyranodipyrazolones on Graphite Oxide Supported Silver Nanoparticles

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Heck and Sonogashira Reactions on Magnetic Cobalt Nanoparticles
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Alkyne Activation by a Porous Polymeric Silver Catalyst

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Aerobic Oxidation of Benzylic Alcohols on Cu–Pd Nanoparticles

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Flow Dehydration and Hydrogenation of Allylic Alcohols

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Rapid Cyanosilylation of Ketones on Montmorillonite K10

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Heck Reaction on Palladium Nanoparticles Supported on Polymer-Modified Silica

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Semihydrogenation of Alkynes on Silica-Supported Cobalt Nanoparticles

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Hydrogenation of Nitroarenes on Platinum–Tin Oxide Core–Shell Nanoparticles

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Microporous Polymer Supported Palladium Catalyst for Oxidative Heck Reactions

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An Immobilized Bisphosphine as Efficient Ligand in Co, Ni, and Cu Catalysis

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0669
Heterogeneous Copper Catalysts for the Synthesis of Indole-2-Carboxylic Esters

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0670
Hydrogenation of N-Heterocycles on ‘Naked’ Iridium(IV) Oxide Nanoparticles

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Hydrogenation of Nitrobenzenes over γ-Fe₂O₃/Mesoporous Carbon

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Erratum
672
Total Synthesis of (±)-Andirolide N

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