Synfacts

Issue 09 · September 2017

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A140
SYNFORM ISSUE 2017/09 FREE ACCESS

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Synthesis of Natural Products and Potential Drugs
z0895
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0895
Synthesis of (±)-Waihoensene FREE ACCESS

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0896
Synthesis of P4Q-391

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0897
Synthesis of Vericiguat FREE ACCESS

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0898
Syntheses of Ovafolinin A and B

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0899
Synthesis of (–)-Tubingensin B

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0900
Synthesis of a Serine Hydroxymethyltransferase Inhibitor

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0901
Total Syntheses of Cheloviolenes A and B and Dendrillolide C

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0902
Stille Cross-Coupling Route to HIV NNRTI Doravirine Analogues

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0903
Syntheses of (–)-Alotaketal A and (–)-Phorbaketal

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0904
Synthesis of (S)-Duloxetine

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0905
Total Syntheses of Aspidosperma Alkaloids

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0906
Biomimetic Syntheses of (±)-Homodimericin A

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Synthesis of Heterocycles
z0907
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0907
Catalytic C(sp³)–CF₃ Bond Formation

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0908
Scalable Synthesis of Haloquinolin-2(1H)-ones and Quinolines

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0909
Synthesis of 2-Spiropiperidines by the Aza-Maitland–Japp Reaction

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0910
Conversion of Endoperoxides into Furans by the Appel Reaction

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0911
Synthesis of Tetrahydropyridines by Enantioselective Cyclization of 1,6-Dienes

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0912
Visible Light Assisted Synthesis of Imidazoles by Intramolecular C–H Imination

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0913
Synthesis of Isoquinolinones by Amide Umpolung

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0914
Copper-Catalyzed Annulation of Tetronic Acids with Azirines: Scope and Mechanism

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0915
Chiral Binaphthylsulfonate Cluster Catalyst for Cycloaddition Reaction

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0916
Diastereoselective Synthesis of Difluoromethylated Spirooxindoles

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0917
Synthesis of Dihydrophenanthridines by Dehydrogenative Coupling

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0918
Asymmetric Synthesis of Chiral 3,4-Dihydro-2H-pyrancarbonitriles

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0919
One-Pot Synthesis of 1,2-Disubstituted Benzimidazoles

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0920
Rhodium(III)-Catalyzed Synthesis of Pyrano[2,3,4-de]-quinolines

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Synthesis of Materials and Unnatural Products
z0921
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0921
1,3- and 1,4-Benzdiyne Equivalents

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0922
Ramping up to Thiophene: Sulfur-Containing Helicenes

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0923
Utilizing Cyclopentadiene for the Design of New Polyenyne Motifs FREE ACCESS

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0924
Facile Route to Fused Cyclobutanes

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0925
Longer Arms Make It More Optically Active

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0926
Catch and Release: Reversible Binding in a pH-Responsive Macrocycle

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0927
Switching up the Synthesis of Molecular Switches

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0928
Compounds with ABC’s (Electron-Acceptor, Boron, Chromophore)

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0929
Bent Porphyrin Tapes Enabled by Seven-Membered Rings

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0930
A New Addition to the BN-Phenanthrene Family

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0931
π-Extended Antiaromatic Polycyclic Hydrocarbons

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0932
Carbon Nanostructures for a 3D World

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Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
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0933
Silver-Catalyzed Intramolecular Aziridination

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0934
Rhodium-Catalyzed Asymmetric Synthesis of γ-Keto Carboxylic Acids

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0935
Enantioselective Palladium-Catalyzed Synthesis of Diarylsulfoxides FREE ACCESS

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0936
Palladium-Catalyzed Reaction of α,α-Dithioacetonitriles with Imines

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0937
Asymmetric Copper Hydride Catalyzed Coupling Reaction to Access Chiral Ketones FREE ACCESS

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0938
Enantioselective Hydroamination of Olefins Forming Chiral Aziridines

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0939
Iridium-Catalyzed Asymmetric Arylation of Allylic Alcohols with Anilines

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0940
Spirocyclic Ketones through a Copper-Catalyzed Arylation-Semipinacol Rearrangement

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0941
Asymmetric Dysprosium-Catalyzed [3+2] Cycloaddition Reaction

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0942
Asymmetric Synthesis of γ-Alkenyl Butenolides

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0943
Asymmetric Nickel-Catalyzed Desymmetrization Reaction

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0944
Copper-Catalyzed [2+2] Cycloaddition of Quinones and Fulvenes

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0945
Chiral-at-Metal Iridium(III) Nucleophilic Catalyst

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0946
Construction of Oxindoles Catalyzed by a Chiral-at-Rhodium Complex

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0947
Copper/Borinic Acid-Catalyzed Enantioselective Propargylation of Polyols

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0948
Enantioselective Palladium-Catalyzed Diboration Reaction

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0949
Cyclopropanation of β,γ-Unsaturated α-Keto Esters with Diazo Esters

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0950
Enantioselective Rhodium-Catalyzed Markovnikov Hydroboration of Alkenes

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0951
Asymmetric Carbomagnesiation of Cyclopropanes

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0952
Palladium-Catalyzed Iminoarylation: Domino Narasaka–Heck/Arene C–H Alkylation

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0953
Enantioselective Iridium-Catalyzed Hydro-hydroxymethylation of Trifluoromethyl Allenes

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0954
Enantioselective Radical Addition of CX₄ to Olefins

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0955
Iridium-Catalyzed Enantio- and Diastereoselective Spiroketalization

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0956
Asymmetric Protoboration to Form Chiral α-Amino Boronate Esters

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0957
Synthesis of Dihydrophenazasilines via an Asymmetric 1,5-Palladium Migration

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0958
Stereoselective Synthesis of Aryl Glycines by Ruthenium-Catalyzed Hydrogenation

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0959
Copper-Catalyzed 1,2-Addition of gem-Diborylalkanes to Imines

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0960
Iridium-Catalyzed Asymmetric Hydrogenation of Cyclic Enones

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0961
Copper- and Lewis-Base-Catalyzed Asymmetric Synthesis of Quinolones

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0962
Enantioselective Nickel-Catalyzed Mizoroki–Heck Reaction

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Metal-Mediated Synthesis
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0963
Bi(OTf)₃-Mediated Olefinic Cyclization

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0964
Palladium-Catalyzed Desulfonative Coupling

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0965
Nickel-Catalyzed Reductive Cross-Coupling

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0966
Diastereoselective α-Arylation of Cyclic Nitriles

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0967
Enantioselective Synthesis of Homopropargyl Alcohols

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0968
Selective Addition of Allylboron Compounds to Fluoroalkyl Ketones

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0969
Suzuki–Miyaura Cross-Coupling of N-Acylpyrroles and -Pyrazoles

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0970
Allene Synthesis by Decomposition of Alkynyl N-Nosylhydrazones

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0971
An 3-Aryl H₈-BINOL Ligand for the Alkylation and Arylation of Aldehydes

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0972
Borylative Cyclization of In Situ Generated o-Allenylaryl Nitriles

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0973
Three-Component Coupling between Alkynes, Iodoarenes, and Bis(iodozincio)methane

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0974
Gold-Catalyzed Alkylsulfonylation of Boronic Acids

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0975
Utilizing Flow Conditions for the Production of Grignard Reagents

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0976
ortho-Selective C–H Borylation of 2-Phenylpyridines

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0977
Addition Reactions of Organomagnesium Halides

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Organo- and Biocatalysis
z0979
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0979
Enzyme-Catalyzed Enantioselective Reductive Amination

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0980
Enantioselective Aza-pinacol Rearrangement of Indoles

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0981
Directed Evolution toward an Iron-Heme Enzyme for Asymmetric C–H Amination FREE ACCESS

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0982
Enzymatic Friedel–Crafts Acylation and Fries Rearrangement

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0983
Enantioselective Photocatalytic α-Alkylation of Aldehydes

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0984
Asymmetric α-Fluorination of α-Branched Enals

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0985
Catalyst-Controlled Diastereoselectivity Switch in Conjugate Additions

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0986
Enantioselective Diels–Alder Cycloaddition to Construct Carbazolespirooxindoles

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0987
Organo- and Biocatalytic Sequential Transformation of Alcohols into Amines

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0988
Enantioselective Conjugate Additions of Indoles Catalyzed by Fiaud’s Acid

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Polymer-Supported Synthesis
z0989
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0989
Parallel Carbonylation and Decarbonylative Heck Reaction on Palladium/Carbon FREE ACCESS

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0990
Metal–Organic Frameworks as Multifunctional Heterogeneous Asymmetric Catalysts

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0991
N-Arylation of Anilines and Imidazoles on Copper(II) Oxide Nanoparticles

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0992
Palladium Nanocatalysts for Aryl Halogenation and Cross-Coupling Reactions

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0993
Hydrogenation of Alkynes and Alkenes on Silica-Supported Palladium Nanoparticles

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0994
Controlled Hydrogenation of Alkynes on Photogenerated Palladium Nanoparticles

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0995
Hydrogenation with Ruthenium Nanoparticles in Ionic Liquids

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0996
Dehydrogenative Imine Transformations on a Platinum/Titania Catalyst

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0997
A Polymeric Pyridine–Zinc Catalyst for Synthesis of Cyclic Carbonates

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0998
Synthesis of 2,2-Diphenylethanol Derivatives from Aromatic Aldehydes

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0999
Enantioselective Tandem Hydrogenation/Coupling on a Palladium–Ruthenium Catalyst

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1000
Continuous-Flow Palladium/Carbon-Catalyzed Fujiwara–Moritani Reaction

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1001
Indium-Catalyzed Oxidative Amination of 2-Aminopyridines

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1002
One-Pot Synthesis of Tetrahydropyridines on Graphene Oxide

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1003
Photocatalytic Oxidation with Carbon-Nanodot-Doped Carbon Nitride

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1004
Diazotation of o-Phenylenediamines on Montmorillonite K-10

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