Synthesis

Rubrik: Synthetic Advancements Enabled by Phosphorus Redox Chemistry

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Ausgabe 06/2023

Fujimoto, Hayato; Yamamura, Shisato; Takenaka, Namiki; Tobisu, Mamoru: Phosphine-Catalyzed Z-Selective Carbofluorination of Alkynoates Bearing an N-Heteroarene Unit
https://www.thieme-connect.de/media/synthesis/202306/i_c0369_ga_10-1055_a-1948-3234.gif
Zhang, Li; Shi, Jianxun; Fang, Yewen: An Alternative to the Arbuzov Reaction: Generation and Transformation of α-Dialkyl-Substituted Methylphosphonate Carbanions via an SET Reduction Process
https://www.thieme-connect.de/media/synthesis/202306/i_c0379_ga_10-1055_a-1959-2742.gif
Picthall, Daniel; Surgenor, Brian A.; Kilian, Petr: Convenient and Scalable Synthesis of Aryldichlorophosphines and Primary Arylphosphines via Perthiophosphonic Anhydrides
https://www.thieme-connect.de/media/synthesis/202306/i_c0422_ga_10-1055_a-1994-2301.gif
Woof, Callum R.; Linford-Wood, Thomas G.; Mahon, Mary F.; Webster, Ruth L.: Catalytic Hydrophosphination of Allenes Using an Iron(II) β-Diketiminate Complex
https://www.thieme-connect.de/media/synthesis/202306/i_c0290_ga_10-1055_a-1902-5592.gif
Endo, Chikako; Inoue, Yurika; Maruyama, Toshifumi; Minoura, Mao; Murai, Toshiaki: Two-Step Transesterification of Phosphates, Phosphorothioates, and Phosphonates with a Binaphthyl Group for the Synthesis of P-Chirogenic Phosphates and Phosphonates
https://www.thieme-connect.de/media/synthesis/202306/i_c0357_ga_10-1055_a-1948-3003.gif