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Synthesis 2001; 2001(3): 0389-0392
DOI: 10.1055/s-2001-11426
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A Novel Stereoselective Route to Trifluoromethylated Vinyl Sulfones

Yanchang Shen* , Guoping Wang, Jie Sun
  • *Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Academia Sinica, 345 Linglin Lu, Shanghai 200032, China; Fax + 86(21)64 16 61 28; E-mail: shenyc@pub.sioc.ac.cn
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Publication Date:
31 December 2001 (online)

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A novel stereoselective route to trifluoromethylated vinyl sulfones via sequential transformation of phosphonates is described.

sequential transformations - stereoselectivity - trifluoromethyl compounds - vinyl sulfones - Grignard reagents - fluorine - sulfur