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DOI: 10.1055/a-1972-5978
Broadly Applicable Synthesis of Heteroarylated Dithieno[3,2-b:2′,3′-d]pyrroles for Advanced Organic Materials – Part 2: Hole-Transporting Materials for Perovskite Solar Cells
Abstract
Functionalization of heteroarylated dithieno[3,2-b:2′,3′-d]pyrroles (DTPs) by triarylamines was elaborated to result in novel hole-transport materials (HTMs) for perovskite solar cells. The new HTMs showed promising photovoltaic performance with efficiencies exceeding 18%. A thorough investigation of the electronic and optoelectronic properties revealed that the main efficiency loss mechanisms are not related to the pristine HTM materials but to the suboptimal interface passivation and HTM doping. We provide an optimization strategy for those device fabrication factors, which could render these new materials a potential replacement of current state-of-the-art HTMs.
Key words
organic materials - conjugated molecules - dithienopyrroles - hole-transport materials - perovskite solar cells - optoelectronic propertiesPublication History
Received: 12 August 2022
Accepted after revision: 27 October 2022
Accepted Manuscript online:
04 November 2022
Article published online:
27 January 2023
© 2023. The authors. This is an open access article published by Thieme under the terms of the Creative Commons Attribution-NonDerivative-NonCommercial License, permitting copying and reproduction so long as the original work is given appropriate credit. Contents may not be used for commercial purposes, or adapted, remixed, transformed or built upon. (https://creativecommons.org/licenses/by-nc-nd/4.0/)
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