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CC BY 4.0 · Organic Materials 2024; 06(02): 18-32
DOI: 10.1055/a-2291-8578
Covalent Organic Frameworks (COFs)
Review

Research Progress of β-Ketoenamine-Linked Covalent Organic Frameworks for Photocatalytic Hydrogen Evolution

Ping Xue   #
a   School of Pharmacy, Xianning Medical College, Hubei University of Science and Technology, Xianning, 437100, P. R. of China
,
Mingyuan Li   #
b   College of Chemistry and Molecular Sciences, Hubei Key Laboratory of Electrochemical Power Sources, Wuhan University, Wuhan, 430000, P. R. of China
,
Mi Tang
c   Ministry of Education Key Laboratory for the Green Preparation and Application of Functional Materials, Hubei Key Laboratory of Polymer Materials, Collaborative Innovation Center for Advanced Organic Chemical Materials Co-constructed by the Province and Ministry, School of Materials Science and Engineering, Hubei University, Wuhan, 430062, P. R. of China
,
Zhengbang Wang
c   Ministry of Education Key Laboratory for the Green Preparation and Application of Functional Materials, Hubei Key Laboratory of Polymer Materials, Collaborative Innovation Center for Advanced Organic Chemical Materials Co-constructed by the Province and Ministry, School of Materials Science and Engineering, Hubei University, Wuhan, 430062, P. R. of China
,
Chengliang Wang 
d   School of Integrated Circuits, Wuhan National Laboratory for Optoelectronics (WNLO), Huazhong University of Science and Technology, Wuhan 430074, P. R. of China
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Abstract

β-Ketoamide covalent organic frameworks (COFs), also named Tp-COFs, are considered to be a milestone material in the history of photocatalysts because of their excellent visible-light absorption, high crystallinity, ultra-high stability and structural diversity. In recent years, a large number of Tp-COFs and their composites have been successfully constructed based on molecular or composite engineering strategies, and exhibited splendid photocatalytic water splitting activity. In comparison with a composite strategy, the molecular engineering technique effectively avoids interface problems by designing and preparing frameworks at the molecular level. Therefore, it is necessary to timely summarize the construction of Tp-COF photocatalysts based on the molecular engineering strategy, so as to provide some theoretical basis and enlightenment for the subsequent development of high-performance Tp-COFs. Finally, the shortcomings and challenges of this technique and personal views on the further development of Tp-COFs are presented.

Key words

β-ketoenamine - covalent organic frameworks - photocatalytic - hydrogen

# These authors contributed equally to this work.




Publication History

Received: 25 December 2023

Accepted after revision: 28 February 2024

Accepted Manuscript online:
20 March 2024

Article published online:
29 April 2024

© 2024. The Authors. This is an open access article published by Thieme under the terms of the Creative Commons Attribution License, permitting unrestricted use, distribution, and reproduction so long as the original work is properly cited. (https://creativecommons.org/licenses/by/4.0/).

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Rüdigerstraße 14, 70469 Stuttgart, Germany

 

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