Benzenoid Rings in Triptycene are Communicated

V. J. Chebny; T. S. Navale; R. Shukla; S. V. Lindeman; R. Rathore

doi:10.1055/s-0029-1217931

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Synfacts 2009(10): 1101-1101
DOI: 10.1055/s-0029-1217931

Synthesis of Materials and Unnatural Products

Benzenoid Rings in Triptycene are Communicated

Contributor(s): Timothy M. Swager, Jose M. Lobez
V. J. Chebny, T. S. Navale, R. Shukla, S. V. Lindeman, R. Rathore*
Marquette University, Milwaukee, USA

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Publication History

Publication Date:
22 September 2009 (online)

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Significance

Electron spin resonance (ESR) and photoelectron spectroscopy suggest significant electronic coupling among the three benzenoid rings of triptycene derivatives. Elucidation of the crystal structure of the radical cation of 1 provides further evidence for this hypothesis.