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Synfacts 2010(6): 0672-0672
DOI: 10.1055/s-0029-1219871
DOI: 10.1055/s-0029-1219871
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag
Stuttgart ˙ New York
Asymmetric Hydrovinylation of 1,3-Dienes
R. K. Sharma, T. V. RajanBabu*
The Ohio State University, Columbus, USA
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
20. Mai 2010 (online)
Significance
Building upon previous work in the area of asymmetric hydrovinylation of 1,3-dienes the authors report a cobalt-catalyzed hydrovinylation of unactivated linear 1,3-dienes which occurs with good yields and excellent selectivity. There are few reports of the cobalt-catalyzed codimerization of ethylene with other alkenes forming chiral products and only modest enantioselectivities have been achieved.