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Synfacts 2010(9): 1038-1038  
DOI: 10.1055/s-0030-1257992
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag Stuttgart ˙ New York

Rhodium Chiral Diene Catalyzed Asymmetric Arylation of Aldimines

Contributor(s): Hisashi Yamamoto, Zhi Li
Z. Cao, H. Du*
Beijing National Laboratory of Molecular Sciences, P. R. of China
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Publication History

Publication Date:
23 August 2010 (online)

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Significance

Chiral dienes are a relatively new class of ligands for asymmetric synthesis. In this work, binaphthyl-based chiral dienes are developed as rhodium(I) complexes to catalyze the asymmetric arylation of N,N-dimethylsulfamoyl-protected aldimines with arylboronic acids.