RSS-Feed abonnieren
Bitte kopieren Sie die angezeigte URL und fügen sie dann in Ihren RSS-Reader ein.
https://www.thieme-connect.de/rss/thieme/de/10.1055-s-00000131.xml
PDF herunterladen
Synfacts 2011(7): 0765-0765
DOI: 10.1055/s-0030-1260502
DOI: 10.1055/s-0030-1260502
Metal-Mediated Synthesis
© Georg Thieme Verlag
Stuttgart ˙ New YorkPd-Catalyzed Pyridine-Directed Aerobic Olefination of Unactivated sp³ C-H Sites
K. J. Stowers, K. C. Fortner, M. S. Sanford*
University of Michigan, Ann Arbor, USA
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
17. Juni 2011 (online)
Significance
A new palladium/polyoxometalate-catalyzed aerobic olefination of unactivated sp³ C-H bonds has been developed. Nitrogen-containing heterocycles act as directing groups and the products undergo reversible intramolecular Michael addition to form bicyclic nitrogen-containing scaffolds.