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Synlett 2013; 24(1): 1-5
DOI: 10.1055/s-0032-1317684
DOI: 10.1055/s-0032-1317684
synpacts
Ketone-Based Transition-Metal-Catalyzed Carbon–Carbon and Carbon– Hydrogen Bond Activation: Exploratory Studies
Further Information
Publication History
Received: 12 September 2012
Accepted after revision: 01 November 2012
Publication Date:
27 November 2012 (online)
Dedicated to Professor Barry M. Trost
Abstract
The importance and ubiquity of ketone functional groups in organic synthesis has always been a driving force for discovering new modes of reactivity. Stimulated by the challenges of fused-ring synthesis and ketone alkylation, we summarize here our exploratory studies on ketone-based transition-metal-catalyzed carbon–carbon and carbon–hydrogen bond activation.
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For recent reviews, see:
For reviews on removable DGs, see:
Aminopyridines have been used in aldehyde carbon–hydrogen bond activation; for seminal work and a review, see: