Synlett 2013; 24(13): 1606-1613
DOI: 10.1055/s-0033-1339299
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© Georg Thieme Verlag Stuttgart · New York

Manganese-Mediated C–C Bond Formation via C–H Activation: From Stoichiometry to Catalysis

Congyang Wang*
Beijing National Laboratory of Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. of China   Fax: +86(10)82615073   Email: wangcy@iccas.ac.cn
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Further Information

Publication History

Received: 04 May 2013

Accepted after revision: 03 June 2013

Publication Date:
11 July 2013 (online)

Abstract

C–H activation is an emerging powerful strategy to functionalize organic molecules alternative to traditional synthetic tools. Despite being cheap and abundant in the earth’s crust, manganese is far less studied within the realm of C–H activation, in particular for C–C bond formation, compared to ‘noble’ transition metals. Herein, we provide a state-of-the-art review on Mn-mediated C–C bond-forming reactions, both stoichiometric and catalytic, via C–H bond activation.

 
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