Synlett 2015; 26(08): 997-1002
DOI: 10.1055/s-0034-1380167
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© Georg Thieme Verlag Stuttgart · New York

Recent Development in N-Auxilixary-Assisted Intramolecular Amination for Amine Substrates

Chao Wang
Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, P. R. of China   Email: yszhao@suda.edu.cn
,
Jian Han
Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, P. R. of China   Email: yszhao@suda.edu.cn
,
Yingsheng Zhao*
Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, P. R. of China   Email: yszhao@suda.edu.cn
› Author Affiliations
Further Information

Publication History

Received: 25 November 2014

Accepted after revision: 07 January 2015

Publication Date:
09 February 2015 (online)

Abstract

Direct coupling of N–H with C–H has aroused great attention in the last decades; during which the directing-group-assisted intramolecular C–N bond formation via transition metal has been achieved significant progress. Herein, we highlight the recent development in the directing-group-assisted intramolecular amination for amine substrates to build the important N-containing heterocyclic compounds.

1 Introduction

2 Triflamide-Promoted Intramolecular Amination

3 Picolinamide-Assisted Intramolecular Amination

4 Palladium-Catalyzed Intramolecular Amination under Assistance of Oxalyl Amide

5 Conclusion

 
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