Synlett
DOI: 10.1055/s-0040-1707275
synpacts

Catalyst Development in the Dehydrogenative Borylation of Alkenes for the Synthesis Vinylboronate Esters

Sida Li
a  State Key Laboratory for Oxo Synthesis and Selective Oxidation, Suzhou Research Institute of LICP Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences, Lanzhou, 730000, P. R. of China   Email: lipengwu@licp.cas.cn
b  University of Chinese Academy of Sciences, Beijing, 100049, P. R. of China
,
Xin Cui
a  State Key Laboratory for Oxo Synthesis and Selective Oxidation, Suzhou Research Institute of LICP Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences, Lanzhou, 730000, P. R. of China   Email: lipengwu@licp.cas.cn
,
Yue Wang
a  State Key Laboratory for Oxo Synthesis and Selective Oxidation, Suzhou Research Institute of LICP Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences, Lanzhou, 730000, P. R. of China   Email: lipengwu@licp.cas.cn
,
Lipeng Wu
a  State Key Laboratory for Oxo Synthesis and Selective Oxidation, Suzhou Research Institute of LICP Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences, Lanzhou, 730000, P. R. of China   Email: lipengwu@licp.cas.cn
b  University of Chinese Academy of Sciences, Beijing, 100049, P. R. of China
› Author Affiliations
We are grateful to the National Natural Science Foundation of China (21901247, 91845108, 21902167), the Natural Science Foundation of Jiangsu Province (BK20180246), and the Innovation and Entrepreneurship Talents Plan of Jiangsu Province for their generous financial support.


Abstract

Catalytic dehydrogenative borylation of alkenes provides an efficient and straightforward method for the preparation of synthetically useful vinylboronate esters. Here, we present a summary of developments and recent advances in this area, classified according to the various reactants and catalyst systems.

1 Introduction

2 Catalytic Dehydrogenative Borylation of Alkenes by Using Boranes

3 Catalytic Dehydrogenative Borylation of Alkenes by Using Diboranes

4 Zirconium-Catalyzed H 2 –Acceptorless Dehydrogenative Borylation of Alkenes with Boranes

5 Conclusion and Outlook



Publication History

Received: 21 May 2020

Accepted after revision: 03 August 2020

Publication Date:
22 September 2020 (online)

© 2020. Thieme. All rights reserved

Georg Thieme Verlag KG
Rüdigerstraße 14, 70469 Stuttgart, Germany

 
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