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Synlett 2021; 32(02): 102-108
DOI: 10.1055/s-0040-1707275
DOI: 10.1055/s-0040-1707275
synpacts
Catalyst Development in the Dehydrogenative Borylation of Alkenes for the Synthesis Vinylboronate Esters
We are grateful to the National Natural Science Foundation of China (21901247, 91845108, 21902167), the Natural Science Foundation of Jiangsu Province (BK20180246), and the Innovation and Entrepreneurship Talents Plan of Jiangsu Province for their generous financial support.
Abstract
Catalytic dehydrogenative borylation of alkenes provides an efficient and straightforward method for the preparation of synthetically useful vinylboronate esters. Here, we present a summary of developments and recent advances in this area, classified according to the various reactants and catalyst systems.
1 Introduction
2 Catalytic Dehydrogenative Borylation of Alkenes by Using Boranes
3 Catalytic Dehydrogenative Borylation of Alkenes by Using Diboranes
4 Zirconium-Catalyzed H 2 –Acceptorless Dehydrogenative Borylation of Alkenes with Boranes
5 Conclusion and Outlook
Publication History
Received: 21 May 2020
Accepted after revision: 03 August 2020
Article published online:
22 September 2020
© 2020. Thieme. All rights reserved
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