Metal Salen- and Salphen-Containing Organic Polymers: Synthesis and Applications

Sven M. Elbert; Michael Mastalerz

doi:10.1055/s-0040-1708501

CC BY-NC-ND 4.0 · Organic Materials 2020; 02(02): 182-203
DOI: 10.1055/s-0040-1708501

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The Author(s). This is an open access article published by Thieme under the terms of the Creative Commons Attribution-NonDerivative-NonCommercial-License, permitting copying and reproduction so long as the original work is given appropriate credit. Contents may not be used for commercial purposes, or adapted, remixed, transformed or built upon. (https://creativecommons.org/licenses/by-nc-nd/4.0/). (2020) The Author(s).

Metal Salen- and Salphen-Containing Organic Polymers: Synthesis and Applications

Sven M. Elbert

^aOrganisch-Chemisches Institut, Ruprecht-Karls-Universität Heidelberg, Im Neuenheimer Feld 270, 69120 Heidelberg, Germany

,

Michael Mastalerz

^aOrganisch-Chemisches Institut, Ruprecht-Karls-Universität Heidelberg, Im Neuenheimer Feld 270, 69120 Heidelberg, Germany

› Institutsangaben

Abstract

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Abstract

The properties of organic polymeric materials can be chemically fine-tuned by the implementation of functional groups or units within the backbone. Especially the inclusion of coordinated metal centers offers a nearly infinite toolbox to adjust properties and thus potential applications. In particular, salen and salphen complexes are widely known to be highly efficient homogenous catalysts. They are also used as luminescent materials and devices or as supramolecular building blocks. This review focusses on the class of salen- and salphen-containing organic polymers, from 1D to 3D. Besides the comparison of synthetic polymerization methods, properties and applications are discussed, with an emphasis on porous 2D and 3D polymeric metal salphens and salens for heterogeneous catalysis and gas sorption.

Key words

Porous polymers - heterogeneous catalysis - conductive films - salens - salphens - gas sorption

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