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Synlett 2002(8): 1211-1222
DOI: 10.1055/s-2002-32946
DOI: 10.1055/s-2002-32946
ACCOUNT
© Georg Thieme Verlag Stuttgart · New YorkDevelopment of Palladium-Catalyzed Cycloalkenylation and its Application to Natural Product Synthesis
Further Information
Received
25 September 2001
Publication Date:
25 July 2002 (online)
Publication History
Publication Date:
25 July 2002 (online)
Abstract
To solve the drawback (considerable decrease in yield on a large scale) of cycloalkenylation employing stoichiometric amounts of Pd(OAc)2, a novel palladium-catalyzed cycloalkenylation has been developed. Stereoselective total syntheses of several bioactive terpenoids have been achieved by means of the above catalytic reaction.
Key words
cycloalkenylation - natural product - catalytic reaction - bioactive terpenoid
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