Ti-Catalyzed Reductive Coupling of Terpenic Allylic Halides

A. F. Barrero; M. Mar Herrador; J. F. Quílez del Moral; P. Arteaga; J. Arteaga; M. Piedra; E. M. Sánchez

doi:10.1055/s-2005-872131

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Synfacts 2005(1): 0157-0157
DOI: 10.1055/s-2005-872131

Metal-Mediated Synthesis

Ti-Catalyzed Reductive Coupling of Terpenic Allylic Halides

Contributor(s): Paul Knochel, Andrei Gavryushin
A. F. Barrero*, M. Mar Herrador, J. F. Quílez del Moral, P. Arteaga, J. Arteaga, M. Piedra, E. M. Sánchez
University of Granada, Spain

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Publication History

Publication Date:
21 September 2005 (online)

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Significance

A mild procedure for the α,α-homocoupling of allylic halides is applied for the synthesis of various terpene frameworks. A catalytic amount of Cp₂TiCl₂ and an excess of Mn as a reducing agent are required for this transformation.