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Synfacts 2006(5): 0483-0483
DOI: 10.1055/s-2006-934433
DOI: 10.1055/s-2006-934433
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag Stuttgart · New York
Stereoselective Synthesis of Catalytically Active Mo3CuS4 Clusters
M. Feliz, E. Guillamón, R. Llusar*, C. Vicent, S. Stiriba, J. Pérez-Prieto, M. Barberis
Universitat Jaume I, Castelló and Universitat de Valencia, Burjasot, Spain
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
21. April 2006 (online)

Significance
The authors have shown that chiral cubane-type structures of clusters can be excised with a chiral diphosphine. This chiral, enantioenriched cluster was shown to be a viable catalyst for both the intra- and intermolecular asymmetric cyclopropanation of diazo compounds (up to 20 and 21% ee, respectively).