Synthetic Use of Molecular Iodine for Organic Synthesis

Hideo Togo; Shinpei Iida

doi:10.1055/s-2006-950405

ACCOUNT

Synthetic Use of Molecular Iodine for Organic Synthesis

Hideo Togo*, Shinpei Iida
Graduate School of Science and Technology, Chiba University, Yayoi-cho 1-33, Inage-ku, Chiba 263-8522 Japan
e-Mail: togo@faculty.chiba-u.jp;

Abstract

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Abstract

The synthetic use of molecular iodine is described. Iodine is a universal oxidizing agent, especially for the oxidation of alcohols and aldehydes to esters, nitriles and amides. Further applications are the introduction of protecting groups, deprotection, iodocyclization, C-C bond formation, and formation of heterocycles.

1 Introduction
2 Oxidation of Alcohols and Aldehydes to Esters, Nitriles, Amides
3 Oxidation of Sulfides
4 Oxidation to Aromatics
5 Introduction of Protecting Groups
6 Deprotection
7 Iodocyclization
8 C-C Bond Formation
9 Formation of Heterocycles
10 Others

Key words

iodine - oxidation - protection - deprotection - iodocyclization - heterocycles

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References

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