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Synlett 2006(14): 2159-2175
DOI: 10.1055/s-2006-950405
DOI: 10.1055/s-2006-950405
ACCOUNT
© Georg Thieme Verlag Stuttgart · New YorkSynthetic Use of Molecular Iodine for Organic Synthesis
Further Information
Received
13 February 2006
Publication Date:
24 August 2006 (online)
Publication History
Publication Date:
24 August 2006 (online)
Abstract
The synthetic use of molecular iodine is described. Iodine is a universal oxidizing agent, especially for the oxidation of alcohols and aldehydes to esters, nitriles and amides. Further applications are the introduction of protecting groups, deprotection, iodocyclization, C-C bond formation, and formation of heterocycles.
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1 Introduction
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2 Oxidation of Alcohols and Aldehydes to Esters, Nitriles, Amides
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3 Oxidation of Sulfides
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4 Oxidation to Aromatics
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5 Introduction of Protecting Groups
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6 Deprotection
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7 Iodocyclization
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8 C-C Bond Formation
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9 Formation of Heterocycles
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10 Others
Key words
iodine - oxidation - protection - deprotection - iodocyclization - heterocycles
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