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Synfacts 2007(7): 0744-0744
DOI: 10.1055/s-2007-968644
DOI: 10.1055/s-2007-968644
Metal-Mediated Synthesis
© Georg Thieme Verlag Stuttgart · New York
N-Imination of Boronic Acids and Organostannanes with O-Acyl Ketoximes
S. Liu, Y. Yu, L. S. Liebeskind*
Emory University, Atlanta, USA
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
22. Juni 2007 (online)
Significance
The reaction of oxime O-carboxylates with boronic acids or organostannanes grants a novel and easy synthetic access to the class of imines. It displays a broad functional group tolerance including even the very sensitive aldehydic and phenolic groups. The stereochemistry of this reaction, however, has yet to be improved.