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Synfacts 2007(7): 0768-0768  
DOI: 10.1055/s-2007-968698
Polymer-Supported Synthesis
© Georg Thieme Verlag Stuttgart · New York

Oxidation of Alcohol Using Macroporous Polystyrene-Supported IBX Amide

Contributor(s): Yasuhiro Uozumi, Yutaka Matsuura
H.-S. Jang, W.-J. Chung, Y.-S. Lee*
Seoul National University, Korea
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Publication History

Publication Date:
22 June 2007 (online)

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Significance

Macroporous polystyrene-supported IBX amide 3 (MPS-IBX) was prepared in two simple steps from resin 1. The polymeric reagent 3 was evaluated for its efficiency of alcohol oxidation giving to the carbonyl compounds in various solvents (10 examples). The reduced MPS-IBX amide resin, the co-product of the oxidation, was activated by oxidation with tetrabutylammonium oxone and reused five times.