Subscribe to RSS
Please copy the URL and add it into your RSS Feed Reader.
https://www.thieme-connect.de/rss/thieme/en/10.1055-s-00000131.xml
Synfacts 2008(4): 0363-0363
DOI: 10.1055/s-2008-1042849
DOI: 10.1055/s-2008-1042849
Synthesis of Materials and Unnatural Products
© Georg Thieme Verlag Stuttgart · New York
Metalation-Triggered Möbius Aromaticity
Y. Tanaka, S. Saito, S. Mori, N. Aratani, H. Shinokubo, N. Shibata, Y. Higuchi, Z. S. Yoon, K. S. Kim, S. B. Noh, J. K. Park, D. Kim*, A. Osuka*
Yonsei University, Seoul, Korea; Kyoto University, University of Hyogo and The RIKEN SPring-8 Center, Hyogo, Japan
Further Information
Publication History
Publication Date:
19 March 2008 (online)
Significance
A new way to achieve complexes that exhibit Möbius aromaticity is described. Conjugated oligopyrrolic macrocycles (also known as expanded porphyrins) were locked into a twisted Möbius strip conformation using group 10 metals. Experimental and numerical studies reveal compounds 3, 5, and 7-9 as conformationally locked Möbius aromatic molecules.