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Synfacts 2008(9): 0908-0908  
DOI: 10.1055/s-2008-1077992
Synthesis of Natural Products and Potential Drugs
© Georg Thieme Verlag Stuttgart ˙ New York

Synthesis of (±)-Desoxyhypnophilin

Contributor(s): Philip Kocienski, Arndt W. Schmidt
L. Jiao, C. Yuan, Z.-X. Yu*
Peking University, Beijing, P. R. of China
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Publikationsdatum:
22. August 2008 (online)

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Significance

By utilization of cyclopropyl-substituted dienes as substrates, the scope of Wender’s Rh(I)-catalyzed [5+2+1] cycloaddition of vinyl­cyclopropanes and alkynes has been considerably extended. Thus, the linear triquinane skeleton is constructed in a one-pot procedure.