Molybdenum-Catalyzed Z- and Enantioselective Ring-Opening/Cross-Metathesis
Reactions

I. Ibrahem; M. Yu; R. R. Schrock; A. H. Hoveyda

doi:10.1055/s-0029-1216715

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Synfacts 2009(6): 0633-0633
DOI: 10.1055/s-0029-1216715

Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions

Molybdenum-Catalyzed Z- and Enantioselective Ring-Opening/Cross-Metathesis Reactions

Contributor(s): Hisashi Yamamoto, Pingfan Li
I. Ibrahem, M. Yu, R. R. Schrock, A. H. Hoveyda*
Boston College, Chestnut Hill, and Massachusetts Institute of Technology, Cambridge, USA

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Publication History

Publication Date:
25 May 2009 (online)

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Significance

Highly Z- and enantioselective ring-opening/cross-metathesis reaction is developed by using a sterically less demanding adamantylimido ligand to generate in situ chiral stereogenic-at-Mo complex is generated with bispyrrolide with monoprotected binaphthol.