Diastereoselective Ruthenium-Catalyzed Aminoallylation

E. Skucas; J. R. Zbieg; M. J. Krische

doi:10.1055/s-0029-1217150

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Synfacts 2009(6): 0631-0631
DOI: 10.1055/s-0029-1217150

Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions

Diastereoselective Ruthenium-Catalyzed Aminoallylation

Contributor(s): Mark Lautens, David A. Candito
E. Skucas, J. R. Zbieg, M. J. Krische*
University of Texas at Austin, USA

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Publication History

Publication Date:
25 May 2009 (online)

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Significance

The authors report a highly diastereoselective anti-aminoallylation of aldehydes under ruthenium-catalyzed transfer hydrogenation conditions providing 1,2-amino alcohols. Previous reports of ruthenium-catalyzed allylations lacked stereocontrol.