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Synfacts 2010(9): 1007-1007  
DOI: 10.1055/s-0030-1257919
Synthesis of Materials and Unnatural Products
© Georg Thieme Verlag Stuttgart ˙ New York

Peripheral Coating Effect

Contributor(s): Timothy M. Swager, Shuang Liu
N. Shibata*, B. Das, E. Tokunaga, M. Shiro, N. Kobayashi*
Nagoya Institute of Technology, Tohoku University, Sendai and Rigaku Corporation, Tokyo, Japan
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Publication History

Publication Date:
23 August 2010 (online)

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Significance

The authors report the synthesis of trifluoroethoxy-substituted subphthalocyanine (SubPc, 1). The peripheral coating improves the yields of axial ligand substitution reactions and prevents aggregation, as compared to the pristine- and fluorine-substituted SubPcs.