Nickel-Catalyzed Reductive Cleavage of Aryl Ethers

doi:10.1055/s-0030-1259422

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Synfacts 2011(3): 0319-0319
DOI: 10.1055/s-0030-1259422

Metal-Mediated Synthesis

Nickel-Catalyzed Reductive Cleavage of Aryl Ethers

Contributor(s): Paul Knochel, Andreas K. Steib
P. Álvarez-Bercedo, R. Martín*
Institute of Chemical Research of Catalonia, Terragona, Spain

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Publikationsverlauf

Publikationsdatum:
16. Februar 2011 (online)

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Significance

A catalytic reductive cleavage of inert C-O bonds of aryl methyl ethers as removable directing groups is described. The method uses Ni(cod)₂ in catalytic amounts and is achieved without using halogenated or tin-based precursors.