Two-Component Coupling to Form Benzocycloheptanones

R. Kumar Patti; K. V. Waynant; J. W. Herndon

doi:10.1055/s-0030-1260883

Subscribe to RSS

Please copy the URL and add it into your RSS Feed Reader.

https://www.thieme-connect.de/rss/thieme/en/10.1055-s-00000131.xml

Share / Bookmark

Facebook X Linkedin Weibo

Download PDF

Synfacts 2011(9): 1007-1007
DOI: 10.1055/s-0030-1260883

Metal-Mediated Synthesis

Two-Component Coupling to Form Benzocycloheptanones

Contributor(s): Paul Knochel, Andreas K. Steib
R. Kumar Patti, K. V. Waynant, J. W. Herndon*
New Mexico State University, Las Cruces, USA

Further Information

Publication History

Publication Date:
19 August 2011 (online)

Permissions and Reprints

Significance

A new coupling approach to yield naphthalene-fused cycloheptanones is described. Pentenyl carbene complexes and 2-alkynylbenzoyl derivatives afford the desired products in a single step in a net [5+6] cycloaddition process.