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Synfacts 2011(10): 1073-1073  
DOI: 10.1055/s-0030-1261213
Synthesis of Materials and Unnatural Products
© Georg Thieme Verlag Stuttgart ˙ New York

Palladium Catalysis for Extended PAHs

Contributor(s): Timothy M. Swager, Ggoch Ddeul Han
K. Mochida, K. Kawasumi, Y. Segawa, K. Itami*
Nagoya University, Japan
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Publikationsverlauf

Publikationsdatum:
20. September 2011 (online)

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Significance

Extended polycyclic aromatic hydrocarbons (PAHs) were synthesized via Pd-catalyzed direct arylation of PAHs followed by FeCl3-mediated cyclodehydrogenation. Arylboroxins and o-chloranil as arylating reagents and an oxidant, respectively, were used for C-H bond arylation.