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Synfacts 2013; 9(4): 0393
DOI: 10.1055/s-0032-1318401
DOI: 10.1055/s-0032-1318401
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
Chiral Cyclopentadiene Ligands for the Asymmetric Allylation of Benzamides
Further Information
Publication History
Publication Date:
15 March 2013 (online)
Significance
A class of chiral Cp ligands with tuneable steric parameters is reported and used in the Rh(III)-catalyzed allylation of N-methoxybenzamides. The obtained yields are good and the enantioselectivities excellent.
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Comment
Cyclopentadienyl (Cp) ligands are among the most versatile and frequently used ligands to access robust and highly catalytically active transition-metal complexes. However, there are only a few chiral Cp ligands reported so far.
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