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Synlett 2013; 24(6): 770-772
DOI: 10.1055/s-0032-1318453
DOI: 10.1055/s-0032-1318453
letter
A Concise Synthesis of 4-Vinylphencyphos
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Further Information
Publication History
Received: 10 January 2013
Accepted after revision: 21 February 2013
Publication Date:
06 March 2013 (online)
Abstract
A fast and clean procedure has been found to prepare the 4-vinyl derivative of enantiomerically pure 2-hydroxy-5,5-dimethyl-4-phenyl-1,3,2-dioxaphosphinan-2-oxide, commonly known as phencyphos. This cyclic phosphoric acid is a popular acidic resolving agent. Functionalization opens a route to attachment to surfaces.
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