Synlett 2014; 25(08): 1045-1049
DOI: 10.1055/s-0033-1340674
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© Georg Thieme Verlag Stuttgart · New York

Post-Functionalization: A Useful Method for the Synthesis of Donor-Func­tionalized N-Heterocyclic Carbene–Transition-Metal Catalysts

Zhenbo Mo
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, 200032 Shanghai, P. R. of China   Fax: +86(21)54925460   Email: deng@sioc.ac.cn
,
Liang Deng*
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, 200032 Shanghai, P. R. of China   Fax: +86(21)54925460   Email: deng@sioc.ac.cn
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Further Information

Publication History

Received: 21 November 2013

Accepted after revision: 04 January 2014

Publication Date:
11 February 2014 (online)


Abstract

Functionalized N-heterocyclic carbene ligands are particularly useful and widely applied ligands in transition-metal chemistry and catalysis. In this article we introduce an emerging synthetic method for functionalized N-heterocyclic carbene ligands developed from the reactivity study on cyclometalated N-hetero­cyclic carbene compounds, namely postfunctionalization. The status quo of this method for the preparation of novel donor-functionalized N-heterocyclic carbene complexes and their application in catalysis are discussed.

 
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