Radical Reactions in and on Water Using (Me3Si)3SiH

A. Postigo; S. Kopsov; C. Ferreri; C. Chatgilialoglu

doi:10.1055/s-2007-992470

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Synfacts 2008(2): 0191-0191
DOI: 10.1055/s-2007-992470

Metal-Mediated Synthesis

Radical Reactions in and on Water Using (Me₃Si)₃SiH

Contributor(s): Paul Knochel, Tobias Thaler
A. Postigo, S. Kopsov, C. Ferreri, C. Chatgilialoglu*
ISOF, Consiglio Nazionale delle Ricerche, Bologna, Italy

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Publication History

Publication Date:
23 January 2008 (online)

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Significance

The usefulness of (TMS)₃SiH as expedient radical reducing agent ‘in water’ and ‘on water’ was successfully proven in this article. Hydrophobic compounds could be as efficiently converted as water-soluble substrates.